Takuzo Aida

Takuzo Aida
Born
Takuzo Aida (相田 卓三, Aida Takuzō)

(1956-05-03) 3 May 1956
Oita, Japan
NationalityJapanese
Alma materYokohama National University
The University of Tokyo
AwardsWiley Polymer Chemistry Award (1999)
Humboldt Prize (2011)
Arthur K. Doolittle Award (2012)
Chirality Medal (2017)
Japan Academy Prize (2018)
Scientific career
FieldsChemistry, Supramolecular chemistry, Materials chemistry, Polymer chemistry
InstitutionsThe University of Tokyo
Doctoral advisorProfessor Shohei Inoue
Websitepark.itc.u-tokyo.ac.jp/Aida_Lab/aida_laboratory/index.html

Takuzo Aida (相田 卓三, Aida Takuzō; born May 3, 1956 in Japan) is a Japanese polymer chemist, Deputy Director for the RIKEN Center for Emergent Matter Science (CEMS) and a Distinguished University Professor at the University of Tokyo.

Education

Aida received his Bachelor of Engineering in Physical Chemistry at the Yokohama National University in 1979, before moving to the University of Tokyo for his Master of Engineering (1981) and Doctor of Engineering (1984) degrees in Polymer chemistry following Professor Shohei. He was awarded the Inoue Research Award for Young Scientists for his doctoral work, with the thesis titled Controlled Polymerization by Metalloporphyrins under the supervision of Professor Shohei Inoue.[1]

Career

After completing his doctoral studies, Aida was appointed as an Assistant Professor in the Department of Synthetic Chemistry at the University of Tokyo. In 1986, he was a visiting scholar at the IBM Almaden Research Center. Aida was promoted to the position of Lecturer in 1989, and Associate Professor in 1991, before becomin a full professor in the Department of Chemistry and Biotechnology at the University of Tokyo in 1996. In 2022 he was appointed as a University of Tokyo's Distinguished University Professor.[citation needed]

From 1996 to 1999, Aida served as a researcher in the Japan Science and Technology Agency (JST) PRESTO Fields and Reactions Project. Aida was appointed as a Visiting Professor at the Institute for Molecular Science in Okazaki from 1999 to 2001. He served as the director for the JST ERATO AIDA Nanospace Project from 2000 to 2005,[2] and the JST ERATO–SORST Electronic Nanospace Project from 2005 to 2010. Aida served as the director of the RIKEN Advanced Science Institute from 2008 to 2012. Since 2013 he has been a Deputy Director of the RIKEN Center for Emergent Matter Science (CEMS).[3]

Research

Aida’s research focuses on supramolecular systems with unique properties and functions. He has contributed to the emergence and progress of supramolecular polymerization and reported on non-covalent polymerization by designing an amphiphilic porphyrin that spontaneously forms a 1D cofacial assembly in water as a prototype supramolecular polymer.[4] He also non-covalently achieved nanotubular polymerization,[5] living chain-growth (ring-opening) polymerization,[6] block copolymerization,[7][8][9] stereoselective polymerization,[10][11] and thermally bisignate polymerization.[12] His works have challenged preconceptions in the field of supramolecular chemistry, connected gaps between conventional and supramolecular polymerizations and realized properties unachievable through conventional polymerization.[13]

Immortal polymerization

In 1988, while working on the development of polymerization catalysts, Aida published a prototype of supramolecular polymerization based on his finding of a catalytic version of living polymerization named "immortal polymerization".[4] He also found extrusion polymerization within catalyst-immobilized mesoporous silica, affording extended-chain crystalline polyethylene fibers.[14] He found morphology-dependent energy funneling in photoexcited dendrimers.[15][16]

Chiral polymerization and nanotube materials

After being promoted to full professor, Aida revisited his work on supramolecular polymerization and demonstrated the first homochiral (chiral self-sorting) supramolecular polymerization using a cyclic peptide motif as the chiral monomer.[17] He also synthesized an amphiphilic version of hexabenzocoronene, a "molecular graphene”, and succeeded in its supramolecular nanotubular polymerization, obtaining the first electroconductive supramolecular nanotube.[5] He also utilized the nanographene platform to obtain radial[7][8] and linear[9] supramolecular block copolymers. Aida also found that the supramolecular polymerization of chiral amphiphilic hexabenzocoronenes proceeds in a one-handed helical manner via the majority rule.[10] This work was further extended to the development of a redox-active oligo(o-phenylene) helix[18] and, together with Professor Minghua Liu of the Chinese Academy of Sciences, mirror-symmetry broken helical fibers consisting of an achiral component that serve as a chiral scaffold for transition metal-catalyzed asymmetric reactions.[11] In 2014, Aida obtained a metal-organic nanotube by the supramolecular polymerization of a redox-active ferrocene-cored double-decker tetrapyridyl monomer and demonstrated that this nanotube, upon oxidation, can be cut into gigantic nanorings, which can then be pasted on a negatively charged mica substrate or assembled coaxially to recover the original nanotube upon reduction.[19]

Chain-growth polymerization and stereoselectivity

In 2015, Aida realized the first example of chain-growth supramolecular polymerization.[6]

Thermally bisignate polymerization

In 2017, Aida reported a conceptually new, "thermally bisignate", supramolecular polymerization.[12]

Solvent-free autocatalytic polymerization

In 2021, Aida reported the solvent-free autocatalytic supramolecular polymerization of phthalocyanines.[20]

Poly(ether thiourea) and self-healing glass

His mechanically robust polymer glass which is self-healable at ambient temperatures, poly(ether thiourea).[21]

Editorial positions

Aida has served on the Board of Reviewing Editors for Science Magazine since 2009,[22] on the Advisory Board for the Journal of the American Chemical Society from 2014–2021, and as Associate Editor for the Journal of Materials Chemistry from 2004–2006. He has served on the executive advisory board for Giant.[23]

Awards

  • 1992 – Society of Polymer Science Japan Award[24]
  • 1999 – IBM Science Award[25]
  • 2000 – Nagoya Medal of Organic Chemistry: Silver Medal[26]
  • 2001 – Tokyo Techno Forum Award: Gold Medal[27]
  • 2008 – Coordination Chemistry Award[28]
  • 2008 – Chemical Society of Japan Award[29]
  • 2009 – American Chemical Society Award in Polymer Chemistry
  • 2011 – Fujihara Award[30]
  • 2013 – van't Hoff Award Lecture[31]
  • 2017 – Chirality Medal[32]
  • 2018 – Japan Academy Prize[33]
  • 2019 – Ichimura Prize in Science for Excellent Achievement[34]
  • 2021 – Ryoji Noyori ACES Award[35]
  • 2021 – Netherlands Award for Supramolecular Chemistry[36]

He was elected a foreign member of the Royal Netherlands Academy of Arts and Sciences in 2020.[37] He was elected into the National Academy of Engineering in 2021.[38] He was elected as an International Honorary Member of the American Academy of Arts and Sciences in 2023.[39]

References

  1. ^ Aida, Takuzo; Inoue, Shohei (1996-01-10). "Metalloporphyrins as Initiators for Living and Immortal Polymerizations". Accounts of Chemical Research. 29 (1): 39–48. doi:10.1021/ar950029l. ISSN 0001-4842.
  2. ^ "AIDA Nanospace". Japan Science and Technology Agency. Retrieved 2020-05-08.
  3. ^ "Organization | About CEMS | Center for Emergent Matter Science (CEMS) | RIKEN" (in Japanese). Retrieved 2020-05-07.
  4. ^ a b Aida, Takuzo; Takemura, Akihiko; Fuse, Masahiro; Inoue, Shohei (1988-01-01). "Synthesis of a novel amphiphilic porphyrin carrying water-soluble polyether side chains of controlled chain length. Formation of a cofacial molecular assembly in aqueous media". Journal of the Chemical Society, Chemical Communications (5): 391–393. doi:10.1039/C39880000391. ISSN 0022-4936.
  5. ^ a b Hill, Jonathan P.; Jin, Wusong; Kosaka, Atsuko; Fukushima, Takanori; Ichihara, Hideki; Shimomura, Takeshi; Ito, Kohzo; Hashizume, Tomihiro; Ishii, Noriyuki; Aida, Takuzo (2004-06-04). "Self-Assembled Hexa-peri-hexabenzocoronene Graphitic Nanotube". Science. 304 (5676): 1481–1483. Bibcode:2004Sci...304.1481H. doi:10.1126/science.1097789. ISSN 0036-8075. PMID 15178796. S2CID 39674411.
  6. ^ a b Kang, Jiheong; Miyajima, Daigo; Mori, Tadashi; Inoue, Yoshihisa; Itoh, Yoshimitsu; Aida, Takuzo (2015-02-06). "A rational strategy for the realization of chain-growth supramolecular polymerization". Science. 347 (6222): 646–651. Bibcode:2015Sci...347..646K. doi:10.1126/science.aaa4249. ISSN 0036-8075. PMID 25657246. S2CID 8487579.
  7. ^ a b Yamamoto, Yohei; Fukushima, Takanori; Suna, Yuki; Ishii, Noriyuki; Saeki, Akinori; Seki, Shu; Tagawa, Seiichi; Taniguchi, Masateru; Kawai, Tomoji; Aida, Takuzo (2006-12-15). "Photoconductive Coaxial Nanotubes of Molecularly Connected Electron Donor and Acceptor Layers". Science. 314 (5806): 1761–1764. Bibcode:2006Sci...314.1761Y. doi:10.1126/science.1134441. ISSN 0036-8075. PMID 17170300. S2CID 10615728.
  8. ^ a b Yamamoto, Yohei; Zhang, Guanxin; Jin, Wusong; Fukushima, Takanori; Ishii, Noriyuki; Saeki, Akinori; Seki, Shu; Tagawa, Seiichi; Minari, Takeo; Tsukagoshi, Kazuhito; Aida, Takuzo (2009-12-15). "Ambipolar-transporting coaxial nanotubes with a tailored molecular graphene–fullerene heterojunction". Proceedings of the National Academy of Sciences. 106 (50): 21051–21056. Bibcode:2009PNAS..10621051Y. doi:10.1073/pnas.0905655106. ISSN 0027-8424. PMC 2795534. PMID 19940243.
  9. ^ a b Zhang, Wei; Jin, Wusong; Fukushima, Takanori; Saeki, Akinori; Seki, Shu; Aida, Takuzo (2011-10-21). "Supramolecular Linear Heterojunction Composed of Graphite-Like Semiconducting Nanotubular Segments". Science. 334 (6054): 340–343. Bibcode:2011Sci...334..340Z. doi:10.1126/science.1210369. ISSN 0036-8075. PMID 22021852. S2CID 5458366.
  10. ^ a b Jin, Wusong; Fukushima, Takanori; Niki, Makiko; Kosaka, Atsuko; Ishii, Noriyuki; Aida, Takuzo (2005-08-02). "Self-assembled graphitic nanotubes with one-handed helical arrays of a chiral amphiphilic molecular graphene". Proceedings of the National Academy of Sciences. 102 (31): 10801–10806. Bibcode:2005PNAS..10210801J. doi:10.1073/pnas.0500852102. ISSN 0027-8424. PMC 1182409. PMID 16043721.
  11. ^ a b Shen, Zhaocun; Sang, Yutao; Wang, Tianyu; Jiang, Jian; Meng, Yan; Jiang, Yuqian; Okuro, Kou; Aida, Takuzo; Liu, Minghua (2019-09-04). "Asymmetric catalysis mediated by a mirror symmetry-broken helical nanoribbon". Nature Communications. 10 (1): 3976. Bibcode:2019NatCo..10.3976S. doi:10.1038/s41467-019-11840-3. ISSN 2041-1723. PMC 6726595. PMID 31484928.
  12. ^ a b Venkata Rao, Kotagiri; Miyajima, Daigo; Nihonyanagi, Atsuko; Aida, Takuzo (November 2017). "Thermally bisignate supramolecular polymerization". Nature Chemistry. 9 (11): 1133–1139. Bibcode:2017NatCh...9.1133V. doi:10.1038/nchem.2812. ISSN 1755-4349. PMID 29064499.
  13. ^ Aida, Takuzo (2020). "On Supramolecular Polymerization: Interview with Takuzo Aida". Advanced Materials. 32 (20) 1905445. Bibcode:2020AdM....3205445A. doi:10.1002/adma.201905445. ISSN 1521-4095. PMID 31867791.
  14. ^ Kageyama, Keisuke; Tamazawa, Jun-ichi; Aida, Takuzo (1999-09-24). "Extrusion Polymerization: Catalyzed Synthesis of Crystalline Linear Polyethylene Nanofibers Within a Mesoporous Silica". Science. 285 (5436): 2113–2115. doi:10.1126/science.285.5436.2113. ISSN 0036-8075. PMID 10497126.
  15. ^ Jiang, Dong-Lin; Aida, Takuzo (July 1997). "Photoisomerization in dendrimers by harvesting of low-energy photons". Nature. 388 (6641): 454–456. Bibcode:1997Natur.388..454J. doi:10.1038/41290. ISSN 1476-4687. S2CID 205028355.
  16. ^ Jiang, Dong-Lin; Aida, Takuzo (1998-10-01). "Morphology-Dependent Photochemical Events in Aryl Ether Dendrimer Porphyrins: Cooperation of Dendron Subunits for Singlet Energy Transduction". Journal of the American Chemical Society. 120 (42): 10895–10901. Bibcode:1998JAChS.12010895J. doi:10.1021/ja9823520. ISSN 0002-7863.
  17. ^ Ishida, Yasuhiro; Aida, Takuzo (2002-11-01). "Homochiral Supramolecular Polymerization of an "S"-Shaped Chiral Monomer: Translation of Optical Purity into Molecular Weight Distribution". Journal of the American Chemical Society. 124 (47): 14017–14019. Bibcode:2002JAChS.12414017I. doi:10.1021/ja028403h. ISSN 0002-7863. PMID 12440899.
  18. ^ Ohta, Eisuke; Sato, Hiroyasu; Ando, Shinji; Kosaka, Atsuko; Fukushima, Takanori; Hashizume, Daisuke; Yamasaki, Mikio; Hasegawa, Kimiko; Muraoka, Azusa; Ushiyama, Hiroshi; Yamashita, Koichi (January 2011). "Redox-responsive molecular helices with highly condensed π -clouds". Nature Chemistry. 3 (1): 68–73. Bibcode:2011NatCh...3...68O. doi:10.1038/nchem.900. ISSN 1755-4349. PMID 21160520.
  19. ^ Fukino, Takahiro; Joo, Hyunho; Hisada, Yuki; Obana, Maiko; Yamagishi, Hiroshi; Hikima, Takaaki; Takata, Masaki; Fujita, Norifumi; Aida, Takuzo (2014-05-02). "Manipulation of Discrete Nanostructures by Selective Modulation of Noncovalent Forces". Science. 344 (6183): 499–504. Bibcode:2014Sci...344..499F. doi:10.1126/science.1252120. ISSN 0036-8075. PMID 24786075. S2CID 6360178.
  20. ^ Chen, Zhen; Suzuki, Yukinaga; Imayoshi, Ayumi; Ji, Xiaofan; Rao, Kotagiri Venkata; Omata, Yuki; Miyajima, Daigo; Sato, Emiko; Nihonyanagi, Atsuko; Aida, Takuzo (14 October 2021). "Solvent-free autocatalytic supramolecular polymerization". Nature Materials. 21 (2): 253–261. doi:10.1038/s41563-021-01122-z. ISSN 1476-4660. PMID 34650229. S2CID 234062383.
  21. ^ Yanagisawa, Yu; Nan, Yiling; Okuro, Kou; Aida, Takuzo (2018-01-05). "Mechanically robust, readily repairable polymers via tailored noncovalent cross-linking". Science. 359 (6371): 72–76. Bibcode:2018Sci...359...72Y. doi:10.1126/science.aam7588. ISSN 0036-8075. PMID 29242235.
  22. ^ "Editors and Advisory Boards". Science | AAAS. 2018-01-31. Retrieved 2020-05-07.
  23. ^ "Giant - Editorial Board". Elsevier. Retrieved 2020-05-08.
  24. ^ "学会賞｜高分子学会". main.spsj.or.jp. Retrieved 2020-05-07.
  25. ^ "日本IBM科学賞第13回(1999年)受賞者". IBM (in Japanese). Archived from the original on 2001-04-22. Retrieved 2020-05-07.
  26. ^ "The Nagoya Medal of Organic Chemistry" (PDF). Nagoya University. 2014. Retrieved 2020-05-08.
  27. ^ "ゴールド・メダル賞受賞者一覧". Yomiuri (in Japanese). Archived from the original on 2019-09-02. Retrieved 2020-05-07.
  28. ^ "「貢献賞」受賞者一覧 | 錯体化学会 Japan Society of Coordination Chemistry". www.sakutai.jp (in Japanese). Retrieved 2020-05-07.
  29. ^ "CSJ Awards". The Chemical Society of Japan. Retrieved 2020-05-07.
  30. ^ "無題ドキュメント". www.fujizai.or.jp. Archived from the original on 2016-09-12. Retrieved 2020-05-07.
  31. ^ "Van 't Hoff Award Lectures — KNAW". www.knaw.nl. Archived from the original on 2020-11-26. Retrieved 2020-05-07.
  32. ^ "Chirality 2019 - Sciencesconf.org". chirality2019.sciencesconf.org. Archived from the original on 2020-08-14. Retrieved 2020-05-07.
  33. ^ "The Imperial Prize,Japan Academy Prize,Duke of Edinburgh Prize Recipients | The Japan Academy". www.japan-acad.go.jp. Retrieved 2020-05-07.
  34. ^ "過去の受賞一覧 / 市村賞贈呈 | 公益財団法人 市村清新技術財団". www.sgkz.or.jp. Retrieved 2020-05-07.
  35. ^ "相田卓三副センター長がRyoji Noyori ACES Awardを受賞". www.riken.jp (in Japanese). Retrieved 2022-10-04.
  36. ^ "The Netherlands Award for Supramolecular Chemistry – FMS Research Center". fmsresearch.nl. Retrieved 2022-10-04.
  37. ^ "Takuzo Aida". Royal Netherlands Academy of Arts and Sciences. Archived from the original on 2 May 2020.
  38. ^ "Dr. Takuzo Aida". NAE Website. Retrieved 2023-10-04.
  39. ^ "Takuzo Aida". American Academy of Arts & Sciences. 2023-10-03. Retrieved 2023-10-04.
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